Recent Development Of Vinylogous Mukaiyama Aldol Reactions

February 9, 2018 - Hosokawa, Seijiro

Journal or Book Title: TETRAHEDRON LETTERS

Volume/Issue: 59

Year Published: 2018

The vinylogous Mukaiyama aldol reaction (VMAR) is a powerful tool of polyketide synthesis, which constructs a large size structure by simultaneous introduction of the stereogenic center(s) and the alpha,beta-unsaturated carbonyl group. A variety of stereocontrolled VMARs have been developed and applied to natural product synthesis. This review is focused on recent development of the vinylogous Mukaiyama aldol reaction using s-trans silyl dienolates. (C) 2017 Elsevier Ltd. All rights reserved.

DOI: 10.1016/j.tetlet.2017.11.056

Type of Publication: Article

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